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Date: 21 November 2009
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Two-dimensional conductivity at the surface of organic single crystals  
Topic Name: Two-dimensional conductivity at the surface of organic single crystals
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Category: Electronics

Research persons: R.W.I. de Boer (PhD student), A. Stassen & N. Iosad (Postdocs), A. Morpurgo (PI)

Location: Delft, Germany

Details

Molecular systems, or systems based on small organic molecules, possess interesting and useful electronic properties. The rapidly developing area of organic -or plastic- electronics is based on these materials. The investigations of molecular systems that have been performed in the past have been strongly influenced, in most cases, by the presence of defects or imperfections in the materials used experimentally. This has prevented the systematic investigation of the intrinsic electronic properties of molecular systems.

Our work aims at controlling and understanding the electronic properties of molecular systems. Control can be gained in different ways. The two different ideas on which our research is based are:
1) control the material at the molecular level by acting on the constituent molecules (i.e. the molecular building blocks);
2) control of the charge density in the material -or at its surface- by means of chemical and electrostatic doping.

In this research area, the ability to push the frontier of research beyond its present limits (i.e., truly gaining control over the electronic properties of molecular systems) requires an unprecedented level of control also at the molecular material level. Achieving such a level of material control is an integral part of our research. We do this by working with high-quality single crystals of organic molecules or under extreme UHV conditions (p<10-11 mbar), which allows the minimization of structural and chemical defects in the materials.

The Holy Grail of this work is to fabricate and investigate a high-mobility, organic-based 2D conductor working at cryogenic temperature, in a field effect transistor (FET) configuration. As the electronic transport properties of organic materials are very different from those of more conventional inorganic conductors, such a system would give experimental access to new, unexplored physical phenomena. During the past year, there has been considerable progress in the realization of single crystal FETs and our group has given important contributions to this work.


Tags: Two-dimensional conductivity - organic single crystals - 2D conductor - Organic Crystals -
Research Documents:
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